What Is Ozone and How Does It Work in Water Treatment?
Ozone water treatment uses ozone (O3) — a molecule of three oxygen atoms — as a powerful, chemical-free oxidising agent to disinfect and purify water. With an oxidation potential of 2.08 V compared with 1.36 V for chlorine, ozone is roughly 1.5x more reactive, able to attack the cell walls of bacteria and viruses, break down organic compounds causing colour and odour, and still decompose back to ordinary oxygen (O2) within minutes, leaving no chemical residue in the treated water.
That residue-free decay is the defining advantage of ozone water treatment over conventional chlorination. There is no need to neutralise a disinfection chemical after the contact stage, and no formation of halogenated by-products — the trihalomethanes (THMs) and haloacetic acids (HAAs) that form when chlorine reacts with natural organic matter (NOM). For drinking-water plants, packaged-water bottlers, STPs, ETPs, swimming pools, and industrial process water across India, those two benefits together explain why ozone has become the preferred disinfection technology in projects where both water quality and regulatory compliance matter.
How Ozone Is Generated On-Site
Ozone cannot be stored or transported — it must be generated at the point of use, typically a few metres from the contact vessel. The dominant industrial method is corona discharge (CD), which replicates the natural process that creates the fresh smell after a thunderstorm. A dried feed gas is passed through a high-voltage electrical discharge gap between two dielectric electrodes; the energy dissociates O2 molecules, which then recombine in triplets to form O3. The ozone concentration in the output stream — 1 to 4 wt% for air-fed units and 6 to 14 wt% for oxygen-fed units — depends on applied voltage, electrode gap, cooling efficiency, and the dew point and oxygen content of the feed gas.
Lotus Ozone Tech designs and manufactures its ozone generators using DSC (Dielectric Surface Coated) ceramic electrodes, built entirely in-house at our Chennai facility. Ceramic dielectric cells run cooler and last longer than glass-dielectric equivalents, improving energy efficiency — measured in Wh per gram of ozone produced — and reducing maintenance intervals. For high-concentration applications such as advanced oxidation processes (AOP) for refractory COD in industrial wastewater, our generators can be paired with on-site PSA oxygen plants to achieve the feed-gas purity that shifts ozone yield and efficiency upward.
- Air-fed generators: 1–4 wt% O3 output, lower capital cost, suitable for most disinfection duties
- Oxygen-fed generators: 6–14 wt% O3 output, more ozone per unit of electricity, preferred for AOP and high-dose applications
- Feed gas must be dried to a dew point below -40 degrees C to prevent electrode degradation and NOx formation
- Cooling — air or water — is required to maintain ozone yield: generation produces heat that suppresses output if unmanaged
The Contact Stage: Getting Ozone into Water
Generating ozone is only half the job. Efficient mass transfer of O3 gas into the liquid phase is equally critical, because unreacted ozone that escapes to the atmosphere is wasted dose — and poses a safety hazard above 0.1 ppm in occupied spaces. The process engineer's objective is to maximise ozone transfer efficiency (OTE), typically targeting 80 to 95%, before residual gas reaches the off-gas destructor.
Three contact methods are common in industrial and municipal systems. A venturi injector uses the pressure drop of flowing water to draw ozone-rich gas in and disperse it as fine bubbles — compact, low-headloss, and widely used for flows up to several hundred m3/h. Submerged bubble diffusers (porous ceramic or PTFE domes in a purpose-built contact tank) suit larger municipal flows where retention time is also needed. Nanobubble generators — which Lotus Ozone Tech offers as part of its nanobubble technology platform — produce sub-micron bubbles with dramatically higher surface area and residence time, improving OTE and extending the oxidation window in lake rejuvenation, high-COD effluent treatment, and aquaculture applications.
- Venturi injectors: self-priming, no power required for the gas side, compact; suited to flows below approximately 500 m3/h
- Bubble diffusers: best for large contact tanks requiring long retention time; require careful hydraulic design to avoid channelling
- Nanobubble contactors: OTE often exceeds 90%; bubbles remain stable in water for minutes to hours, prolonging oxidation contact
- Off-gas destructor (catalytic or thermal) is mandatory to neutralise residual ozone in exhaust; ambient ozone alarm required for occupied spaces
What Does Ozone Remove from Water?
Ozone's high oxidation potential gives it a broad-spectrum target list that no single conventional treatment step can match. Unlike UV disinfection — which damages pathogen DNA but cannot oxidise chemical contaminants — ozone acts simultaneously as a disinfectant and an oxidising agent, addressing both microbiological and chemical impurities in a single treatment stage. This dual action is particularly valuable in India, where source water or effluent quality can combine a heavy microbial load with significant colour, odour, and trace organic contamination from agricultural runoff or industrial discharge.
- Pathogens: bacteria (E. coli, Salmonella, Legionella), viruses, Cryptosporidium and Giardia oocysts — ozone achieves 4-log protozoan inactivation at CT values far lower than chlorine requires
- Colour and turbidity: reactive textile dyes, melanoidins in distillery effluent, natural organic matter (NOM), and humic acids are oxidised and decolourised
- Taste and odour: destroys geosmin, 2-methylisoborneol (MIB), and hydrogen sulphide compounds responsible for earthy or rotten-egg odour in source water
- Iron and manganese: oxidises soluble Fe2+ to Fe3+ and Mn2+ to MnO2, converting them to filterable precipitates removed by downstream media filters
- Emerging contaminants: pesticides, pharmaceutical residues, and endocrine-disrupting compounds (EDCs) are partially or fully mineralised by ozone or O3-based AOP
- Biofilm: degrades the polysaccharide matrix protecting biofilm in distribution pipes and cooling-tower fill — a target that safe residual chlorine concentrations alone frequently cannot reach
Ozone vs Chlorine: A Side-by-Side Comparison
The most common question in any ozone project evaluation is whether ozone is worth choosing over an existing chlorine dosing system. Ozone is the stronger technical choice where water quality requires simultaneous pathogen kill and chemical oxidation, where THM or HAA formation is a compliance concern, or where CPCB reuse-quality standards are tightening beyond what tertiary chlorination can reliably deliver. The comparison below covers the key decision dimensions.
- Oxidation strength — Ozone: 2.08 V; kills protozoa rapidly. Chlorine: 1.36 V; protozoa relatively resistant, long CT value required
- Disinfection by-products — Ozone: bromate forms only when bromide is present in source water, controlled by pH and dose. Chlorine: THMs and HAAs form by reaction with NOM and are regulated under IS 10500 and CPCB discharge norms
- Chemical residual after treatment — Ozone: none; decomposes to O2 within minutes. Chlorine: persists and protects against re-contamination in long distribution mains
- Taste and odour impact — Ozone: removes taste and odour compounds from water. Chlorine: can add chlorinous taste and produces off-flavour compounds by reacting with NOM
- Contact time — Ozone: fast; often seconds to a few minutes for full disinfection. Chlorine: longer CT required, especially at higher pH or against protozoa
- Chemical handling hazard — Ozone: generated on-site with no chemical storage; off-gas destructor required. Chlorine: storage tanks, dosing pumps, and gas-leak risk; particularly serious with chlorine gas cylinders
- Operating cost in India — Ozone: electricity at roughly 6–10 Wh per gram of O3; no chemical purchases or transport costs. Chlorine: chemical cost plus freight; price is volatile with import duties and logistics
Key Applications in Indian Industry and Municipalities
Ozone water treatment is deployed across a wide range of industrial, municipal, and commercial sectors in India. It is best suited where chemical-free treatment is mandatory (food processing, bottled water, pharmaceuticals), where CPCB norms demand tertiary-level disinfection and colour removal from STP or ETP effluent, or where chemical storage and handling create a safety or logistical constraint. Lotus Ozone Tech has delivered more than 1,000 installations across these sectors from its Chennai manufacturing base, including a project for the Department of Atomic Energy.
- STP and sewage tertiary treatment: ozone disinfects and removes residual colour to meet CPCB reuse standards for toilet-flush and landscape irrigation applications
- Effluent treatment plants (ETP): AOP combining ozone with H2O2 or nanobubbles tackles refractory COD and colour in pharma, textile, and distillery wastewater
- Swimming pools: ozone reduces free-chlorine demand by up to 90% and eliminates chloramines responsible for eye irritation and the typical pool smell
- Drinking water and packaged-water bottling: final disinfection with no chemical residual; supports longer product shelf life without preservatives
- Aquaculture and recirculating aquaculture systems (RAS): pathogen control and water clarity improvement; ORP monitoring prevents over-dosing that harms fish
- Cooling towers: controls biofilm, scale, and Legionella without biocide chemicals; reduces blowdown frequency and total water consumption
- Food processing and cold storage: surface sanitation of produce, equipment, and cold-room air in unoccupied periods; leaves no chemical residue on food-contact surfaces
Sizing and Dosing: A Practical Checklist Before You Specify
Ozone dosing is not one-size-fits-all. The required dose — expressed in grams of O3 per cubic metre of water treated (g/m3, equivalent to mg/L) — depends on influent quality, the treatment objective, and the required contact time. Over-sizing wastes energy and capital; under-sizing leaves pathogens or COD in the treated effluent. Work through the following checklist before finalising a system specification or requesting a quotation.
- Define the treatment objective first: disinfection only, or combined disinfection plus colour and COD reduction? The second objective requires 2–5x the dose and a larger contact vessel
- Measure influent quality: COD, colour (Pt/Co units), turbidity, iron, manganese, and total organic carbon (TOC). High organic load creates an ozone demand that must be satisfied before any disinfection credit counts
- Establish peak flow rate: size the generator for peak hourly demand, not daily average — ozone cannot be stored to buffer demand peaks
- Choose feed gas: air-fed units cost less upfront but produce lower-concentration O3; oxygen-fed suits doses above 5 mg/L or installations where space is constrained; dew-point control to -40 degrees C is essential for both options
- Set contact time and vessel volume: 4–10 minutes CT for drinking water disinfection; 10–20 minutes for colour-heavy or high-COD effluent; the contact tank must be sized to deliver this at peak flow
- Specify ORP control for sensitive applications: target 300–400 mV for aquaculture to avoid stressing fish; 650–750 mV for general disinfection; ORP-based dosing avoids both under-treatment and energy-wasting over-dosing
- Plan the off-gas system: the exhaust destructor must be rated for the maximum generator throughput, not steady-state only; include a residual-ozone alarm sensor for any occupied working areas
Is Ozone Water Treatment Right for Your Plant?
If your facility needs chemical-free disinfection, must address colour or taste/odour alongside pathogen removal, or has to meet CPCB reuse or discharge standards that tertiary chlorination alone cannot reliably achieve, ozone water treatment is almost certainly the right technology. Lotus Ozone Tech has been designing and manufacturing ozone systems at its Chennai facility since 2010, with more than 1,000 installations across water, wastewater, aquaculture, food processing, and industrial sectors — all built on 100% in-house components.
To explore the technology further, see our ozone technology overview and the full ozone generator product range. When you are ready to discuss your specific flow rate, inlet water quality, and site constraints, contact our engineering team for a properly sized system recommendation and project quotation.
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